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Oxygen‐deficient water zones in the Baltic Sea promote uncharacterized Hg methylating microorganisms in underlying sediments
Department of Chemistry Umeå University Umeå Sweden;Department of Aquatic Sciences and Assessment SLU Uppsala Uppsala Sweden.ORCID iD: 0000-0001-9143-7061
Department of Ecology, Environment and Plant Sciences Stockholm University Stockholm Sweden;Baltic Sea Centre Stockholm University Stockholm Sweden.ORCID iD: 0000-0001-9005-5168
Department of Ecology, Environment and Plant Sciences Stockholm University Stockholm Sweden;Department of Marine Sciences University of Gothenburg Gothenburg Sweden.ORCID iD: 0000-0003-4366-0677
Department of Marine Biology and Oceanography Institute of Marine Sciences, Spanish National Research Council (CSIC) Barcelona Spain.ORCID iD: 0000-0002-8341-3462
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2022 (English)In: Limnology and Oceanography, ISSN 0024-3590, E-ISSN 1939-5590, Vol. 67, p. 135-146Article in journal (Refereed) Published
Abstract [en]

Human-induced expansion of oxygen-deficient zones can have dramatic impacts on marine systems and itsresident biota. One example is the formation of the potent neurotoxic methylmercury (MeHg) that is mediated bymicrobial methylation of inorganic divalent Hg (HgII) under oxygen-deficient conditions. A negative consequenceof the expansion of oxygen-deficient zones could be an increase in MeHg production due to shifts in microbialcommunities in favor of microorganisms methylating Hg. There is, however, limited knowledge about Hg-methylatingmicrobes, i.e., those carrying hgc genes critical for mediating the process, from marine sediments. Here, weaim to study the presence of hgc genes and transcripts in metagenomes and metatranscriptomes from four surfacesediments with contrasting concentrations of oxygen and sulfide in the Baltic Sea. We show that potential Hgmethylators differed among sediments depending on redox conditions. Sediments with an oxygenated surface featuredhgc-like genes and transcripts predominantly associated with uncultured Desulfobacterota (OalgD group)and Desulfobacterales (including Desulfobacula sp.) while sediments with a hypoxic-anoxic surface included hgccarryingVerrucomicrobia, unclassified Desulfobacterales, Desulfatiglandales, and uncharacterized microbes. Ourdata suggest that the expansion of oxygen-deficient zones in marine systems may lead to a compositional changeof Hg-methylating microbial groups in the sediments, where Hg methylators whose metabolism and biology havenot yet been characterized will be promoted and expand.

Place, publisher, year, edition, pages
2022. Vol. 67, p. 135-146
Keywords [en]
Aquatic Science, Oceanography
National Category
Environmental Sciences
Research subject
Man and the environment
Identifiers
URN: urn:nbn:se:nrm:diva-4298DOI: 10.1002/lno.11981OAI: oai:DiVA.org:nrm-4298DiVA, id: diva2:1614906
Funder
Swedish Environmental Protection AgencySwedish Research Council FormasSwedish Research CouncilAvailable from: 2021-11-28 Created: 2021-11-28 Last updated: 2022-09-14Bibliographically approved

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Capo, EricBroman, EliasBonaglia, StefanoBravo, Andrea G.Bertilsson, StefanSoerensen, Anne L.Pinhassi, JaroneLundin, DanielBuck, MoritzNascimento, Francisco J. A.Björn, Erik
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