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  • 1.
    Bindi, Luca
    et al.
    Università degli Studi di Firenze.
    Holtstam, Dan
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Fantappiè, Giulia
    Università degli Studi di Firenze.
    Andersson, Ulf B
    Luossavaara-Kiirunavaara AB.
    Bonazzi, Paola
    Università degli Studi di Firenze.
    Ferriperbøeite-(Ce), [CaCe3]å=4[Fe3+Al2Fe2+]å=4[Si2O7][SiO4]3O(OH)2, a new mineral of the gatelite supergroup, from the Nya Bastnäs Fe-Cu-REE deposit, Västmanland, Sweden.2018Inngår i: European journal of mineralogy, ISSN 0935-1221, E-ISSN 1617-4011, Vol. 30, s. 537-544Artikkel i tidsskrift (Fagfellevurdert)
  • 2.
    Bonazzi, Paola
    et al.
    Università degli Studi di Firenze.
    Holtstam, Dan
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Bindi, Luca
    Università degli Studi di Firenze.
    Gatelite-supergroup minerals: recommended nomenclature and review2019Inngår i: European journal of mineralogy, ISSN 0935-1221, E-ISSN 1617-4011, Vol. 31, s. 173-181Artikkel i tidsskrift (Fagfellevurdert)
    Fulltekst (pdf)
    fulltext
  • 3.
    Cooper, Mark
    et al.
    University of Manitoba, Winnipeg, Canada.
    Hawthorne, Frank
    University of Manitoba, Winnipeg, Canada.
    Langhof, Jörgen
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Hålenius, Ulf
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Holtstam, Dan
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Wiklundite, ideally Pb2[4](Mn2+,Zn)3(Fe3+,Mn2+)2(Mn2+,Mg)19(As3+O3)2[(Si,As5+)O4]6 (OH)18Cl6, a new mineral from Långban, Filipstad, Värmland, Sweden: Description and crystal structure2017Inngår i: Mineralogical magazine, ISSN 0026-461X, E-ISSN 1471-8022, Vol. 81, nr 4, s. 841-855Artikkel i tidsskrift (Fagfellevurdert)
  • 4.
    Cámara, Fernando
    et al.
    Università degli Studi di Milano,.
    Holtstam, Dan
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Jansson, Nils
    Jonsson, Erik
    SGU.
    Karlsson, Andreas
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Langhof, Jörgen
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Majka, Jaroslaw
    Zetterqvist, Anders
    Zinkgruvanite, Ba4Mn2+4Fe3+2(Si2O7)2(SO4)2O2(OH)2, a new ericssonite-group mineral from the Zinkgruvan Zn-Pb-Ag-Cu deposit, Askersund, Örebro County, Sweden.2021Inngår i: European journal of mineralogy, ISSN 0935-1221, E-ISSN 1617-4011, Vol. 33, nr 6, s. 659-673Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Zinkgruvanite, ideally Ba4Mn2+4Fe3+2(Si2O7)2(SO4)2O2(OH)2, is a new member of the ericssonite group, found in Ba-rich drill core samples from a sphalerite+galena- and diopside-rich metatuffite succession from the Zinkgruvan mine, Örebro county, Sweden. Zinkgruvanite is associated with massive baryte, barytocalcite, diopside and minor witherite, cerchiaraite-(Al) and sulfide minerals. It occurs as subhedral to euhedral flattened and elongated crystals up to 4 mm. It is almost black, semi-opaque with a dark brown streak. The luster is vitreous to sub-adamantine on crystal faces, resinous on fractures. The mineral is brittle with an uneven fracture. VHN100 = 539 and HMohs ~4½. In thin fragments, it is reddish-black, translucent and optically biaxial (+), 2Vz > 70°. Pleochroism is strong, deep brown-red (E ⊥ {001} cleavage) to olive-pale brown. Chemical point analyses by WDS-EPMA together with iron valencies determined from Mössbauer spectroscopy, yielded the empirical formula (based on 26 O+OH+F+Cl anions): (Ba4.02Na0.03)Σ4.05(Mn1.79Fe2+1.56Fe3+0.42Mg0.14Ca0.10Ni0.01Zn0.01)Σ4.03 (Fe3+1.74Ti0.20Al0.06)Σ2.00Si4(S1.61Si0.32P0.07)Σ1.99O24(OH1.63Cl0.29F0.08)Σ2.00. The mineral is triclinic, space group P–1, with unit-cell parameters a = 5.3982(1) Å, b = 7.0237(1) Å, c = 14.8108(4) Å, α = 98.256(2)º, β = 93.379(2)º, γ = 89.985(2)º and V = 554.75(2) Å3 for Z = 1. The eight strongest X-ray powder diffraction lines are [d Å (I%; hkl)]: 3.508 (70; 103), 2.980(70; 11–4), 2.814 (68; 1–22), 2.777 (70; 121), 2.699 (714; 200), 2.680 (68; 20–1), 2.125 (100; 124, 204), 2.107 (96; –221). The crystal structure (R1 = 0.0379 for 3204 reflections) is an array of TS (titanium silicate) blocks alternating with intermediate blocks. The TS blocks consist of HOH sheets (H = heteropolyhedral, O = octahedral) parallel to (001). In the O sheet, the Mn2+-dominant MO(1,2,3) sites give ideally Mn2+4 pfu. In the H sheet, the Fe3+-dominant MH sites and AP(1) sites give ideally Fe3+2Ba2 pfu. In the intermediate block, SO4 oxyanions and eleven coordinated Ba atoms give ideally 2 × SO4Ba pfu. Zinkgruvanite is related to ericssonite and ferro-ericssonite in having the same topology and type of linkage of layers in the TS block. Zinkgruvanite is also closely compositionally related to yoshimuraite, Ba4Mn4Ti2(Si2O7)2(PO4)2O2(OH)2, via the coupled heterovalent substitution 2 Ti4+ + 2 (PO4)3- →2 Fe3+ + 2 (SO4)2-, but presents a different type of linkage. The new mineral probably formed during a late stage of regional metamorphism of a Ba-enriched, syngenetic protolith, involving locally generated oxidized fluids of high salinity.

    Fulltekst (pdf)
    zinkgruvanite
  • 5.
    Cámara, Fernando
    et al.
    Università degli Studi di Milano,.
    Holtstam, Dan
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Karlsson, Andreas
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Skogby, Henrik
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Old samples - new amphiboles2022Inngår i: Abstracts, International Mineralogical Association 23rd General meeting, Lyon, 2022, Vol. 1, s. 42-42Konferansepaper (Annet vitenskapelig)
    Abstract [en]

    The scientific value of old and well-preserved collections is priceless. Samples that already have been studied and described can still give very useful information. For instance, minerals with complex solid solutions like amphiboles sometimes show new compositions that are feasible because of crystal-chemistry and charge arrangements, based on the current classification scheme by Hawthorne et al. (2012) for the amphibole supergroup. In the last four years, a fruitful collaboration between the Swedish Museum of Natural History and the Department of Earth Sciences of the University of Milan has allowed the identification of new amphibole species, recognized by CNMNC-IMA. First of all, we identified hjalmarite, [ANaB(NaMn)CMg5TSi8O22W(OH)2], which is related to richterite via the homovalent substitution [B]Ca2+ → [B]Mn2+, and is the second recognized member of the sodium–(magnesium–iron–manganese) subgroup, after ferri-ghoseite. Sjögren (1891) had described a physically similar, MnO-rich sample from Långban, named “astochit”. A related amphibole, although belonging to a different subgroup, that we have formally described is potassic-richterite, [AKB(NaCa)CMg5TSi8O22W(OH)2]. It was found in a sample from the Pajsberg iron and manganese ore mines, which was originally collected by the mineralogist Lars Johan Igelström, probably in the 1850s. The most recent amphibole we have described is ferri-taramite [ANaB(NaCa)C(Mg3Fe3+2)T(Si6Al2)O22W(OH)2], found in a skarn sample from the Jakobsberg manganese mine: it was once examined by Flink (1914), who noted the unusual character of the amphibole and described it as a “strange hornblende”.

    Fulltekst (pdf)
    fulltext
  • 6.
    Holtstam, Dan
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Cronstedt 300 år2022Inngår i: Geologiskt forum, ISSN 1104-4721, Vol. 114, s. 12-16Artikkel i tidsskrift (Annet (populærvitenskap, debatt, mm))
    Abstract [sv]

    Axel Fredrik Cronstedt (1722-1765) är en av de mest kända svenskarna inom mineralogin. Han beskrev nya grundämnen och mineral samt presenterade ett nydanande klassificeringssystem. Detta byggde på mineralens kemiska sammansättning snarare än deras yttre egenskaper.

  • 7.
    Holtstam, Dan
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Den outsläckliga törsten efter kobolt2019Inngår i: Geologiskt forum, ISSN 1104-4721, Vol. 2019, nr 103, s. 25-28Artikkel i tidsskrift (Annet (populærvitenskap, debatt, mm))
    Abstract [en]

    The shift to electric vehicles and the growing production of rechargeable batteries needed in these have dramatically increased the global demand for cobalt. Most of the metal comes from less stable areas in the world, which makes the supply precarious. The article describes the present situation (in Swedish), and gives a brief overview of the main sources of cobalt in the world today and the prospects for exploiting reserves in Sweden.

  • 8.
    Holtstam, Dan
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Hedins första stuff2023Inngår i: Geologiskt forum, ISSN 1104-4721, Vol. 117, s. 21-21Artikkel i tidsskrift (Annet (populærvitenskap, debatt, mm))
  • 9.
    Holtstam, Dan
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Hubeit från Harstigen - andra lokalen i världen2020Inngår i: Långbansnytt, ISSN 1650-4968, Vol. 26, s. 13-14Artikkel i tidsskrift (Annet (populærvitenskap, debatt, mm))
    Abstract [en]

    Hubeite occurs in an old museum specimen of rhodonite from the Harstigen mine, in a fissure in pyroxene skarn, associated with rhodonite, barite, gonyerite and calcite. Chemical and X-ray crystallographic data are very close to those of the type material from Hubei Province, PR China. A 57Fe Mössbauer spectrum is provided.

  • 10.
    Holtstam, Dan
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Plumbonakrit och somersetit (?) från Långban2020Inngår i: Långbansnytt, ISSN 1650-4968, Vol. 26, s. 20-21Artikkel i tidsskrift (Annet (populærvitenskap, debatt, mm))
    Abstract [en]

    The occurence of plumbonacrite, and possibly somersetite, at the Långban deposit has been verified by powder X-ray diffraction and chemical point analysis (EDS). The minerals are intergrown with hydrocerussite, and coexisting minerals on the crack surface of the specimen, a pinkish carbonate rock with mica, chlorite and minor oxides, are sahlinite, native lead, pyrochroite, calcite and baryte.

  • 11.
    Holtstam, Dan
    Naturhistoriska riksmuseet, Enheten för geovetenskap. Swedish Museum of Natural History.
    Prehistory of an enigmatic mineral: hisingerite2023Inngår i: GFF, ISSN 1103-5897, E-ISSN 2000-0863, Vol. 145, s. 1-3Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    According to most sources, the type locality for the hydrous iron silicate mineral hisingerite is Riddarhyttan, Västmanland, Sweden, first reported in 1828. However, it was described by A.F. Cronstedt as early as 1751 from Väster Silvberg, Dalarna (under the name “kolspeglande järnmalm”), and in 1810 by W. Hisinger from the Gillinge iron mine, Södermanland (“svart stenart”, later “gillingit”). J. Berzelius introduced the presently valid species name (originally spelt “hisingrit”) in 1819. Potential type materials are preserved by the Swedish Museum of Natural History, from Gillinge and Riddarhyttan. A Hisinger specimen from Gillinge has recently been analysed and was shown to contain associated potassic-hastingsite, magnetite and fayalite that explain the previously observed aluminium contents and high density for “gillingit”, compared to pure hisingerite

    Fulltekst (pdf)
    fulltext
  • 12.
    Holtstam, Dan
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Raman spectroscopy as a tool in mineral discoveries2021Inngår i: Extended Abstracts, 9th International Conference Mineralogy and Museums / [ed] Ruslan Kostov, Sofia: Earth and Man National Museum , 2021, s. 50-51Konferansepaper (Annet vitenskapelig)
    Abstract [en]

    Preliminary investigations of unknown minerals are frequently based on physical and optical observations, chemical analysis and collection of powder X-ray diffraction data. At the Swedish Museum of Natural History, laser Raman micro-spectrometry has been adopted as a standard method, which led to discoveries that otherwise might have been unnoted.

    The new mineral garpenbergite (IMA2020-099), with formula Mn6□AsSbO10(OH)2, is found at the Garpenberg Zn-Pb-Ag deposit, Dalarna (Dalecarlia), Sweden. Preliminary data indicated a close relationship to manganostibite, ideally Mn7AsSbO12. The two minerals are not easily distinguished using routine procedures, because of almost identical powder patterns and similar chemical compositions. In the Raman spectra, a characteristic feature, with distinct bands at 3647 and 3622 cm-1 related to OH-stretching vibration modes, appears for garpenbergite only. Structural refinement from single-crystal X-ray diffraction data yielded an orthorhombic unit cell, with a = 8.6919(10), b = 18.927(3), c = 6.1110(6) Å for Z = 4. The crystal structure is distinct by the presence of a vacancy, corresponding to an octahedrally coordinated Mn2+ site in manganostibite (Moore, 1970), and by incorporation of protons via the exchange mechanism Mn2+ + 2O2- → □ + 2(OH)- that leaves the space-group symmetry, Ibmm, invariant.

    Parahibbingite (IMA2020-038a) was recently approved, with the Karee mine in the Bushveld complex, South Africa, as type locality. This mineral, with formula Fe2+2(OH)3Cl, has independently also been identified on samples of corrosion crust from weathered fragments of the Muonionalusta iron meteorite, collected in the Kitkiöjärvi area, Pajala, in northernmost Sweden. From initial energy-dispersive X-ray microanalysis, it was identified as hibbingite or possibly another polymorph of Fe2+2(OH)3Cl , and the identity with the rhombohedral β-form was then confirmed with Raman spectroscopy, when compared with data for the synthetic analogue. A subsequent refinement of the crystal structure, including the hydrogen positions, from single-crystal diffraction data gave a = 6.9362(4), c = 14.6730(11) Å with Z = 6 for the R-3m unit cell, in good agreement with previous Rietveld refinement of synthetic material and corrosion products from artefacts.

    Magnussonite, ca. Mn10As6O18OH2, is a rare arsenite mineral with inferred cubic crystal symmetry that has been the subject of several studies. Brattforsite, ideally Mn19(AsO3)12Cl2 (IMA2019-127), has a similar structural topology as magnussonite and is a monoclinic bona fide Cl-analogue . The close relationship between the two minerals is supported by their resemblance in the Raman spectra overall, but there is also a distinct shift (ca. 30 cm-1) in the bands originating from As-O stretching in the (AsO3)3- groups, related to differences in mean bond lengths between the corresponding atoms.

     

     

     

    Fulltekst (pdf)
    fulltext
  • 13.
    Holtstam, Dan
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Speaking of anniversaries: Who was the first modern mineralogist?2022Inngår i: Geological Society of Sweden, 150 year anniversary meeting, Uppsala, August 17–19 2022, Abstract volume., Uppsala, 2022, Vol. 1, s. 86-87Konferansepaper (Fagfellevurdert)
    Abstract [en]

    Mineralogy is among the oldest sciences and a core discipline of geology. Already in the Neolithic period, the recognition and use of various minerals was important knowledge for humans. Writers of the Antiquity on the subject, Theophrastus and Pliny the Elder, treated rocks and minerals from a natural-philosophical point of view. Polymaths like Avicenna (Persia) and Shen Kuo (China) in the 11th century AD also documented the minerals known to exist then. European authors of the Renaissance, with Georgius Agricola as the foremost, used the intrinsic physical properties of minerals to describe and classify them in systematic way, an approach that essentially established mineralogy as a science. In Sweden, there was little development in the field before the 18th century (a notable exception is the contributions of Urban Hjärne). During the Age of Liberty*, works relating to various aspects of minerals, by natural scientists like Johan Gottschalk Wallerius, Henrik Teofil Scheffer, Carl Linnaeus and Torbern Bergman, came to have a wide influence, far beyond Sweden’s borders. Among the mineralogists active in this dynamic period, Axel Fredrik Cronstedt stands out as an exeptionally innovative and forsighted character.

    Fulltekst (pdf)
    fulltext
  • 14.
    Holtstam, Dan
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Sällsynt sydvästafrikan i värmländsk tappning: yangit från Långban - andra lokalen i världen2022Inngår i: Långbansnytt, ISSN 1650-4968, Vol. 27, s. 25-25Artikkel i tidsskrift (Annet (populærvitenskap, debatt, mm))
    Abstract [en]

    The rare lead silicate mineral yangite, previously only known from the Kombat Mine, Namibia, has been identified in a Långban sample (Canberra stope), in the collection of the Swedish Museum of Natural History. It occurs as elongated whitish crystals in aggregates up to 2 mm, associated with melanotekite, jagoite and quartz. The monoclinic unit-cell parameters obtained from powder X-ray diffraction data are a = 9.597(2), b = 7.281(2), c = 7.968(2) Å, α = 106.03(1)°, β =118.14(1)°, γ = 109.85(1)° and V = 392.7(1) Å3.

  • 15.
    Holtstam, Dan
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Vad betyder ett namn? Om beskrivningar och namngivning av mineral.2018Inngår i: Litofilen, ISSN 1651-6117, Vol. 34, nr 4, s. 7-12Artikkel i tidsskrift (Annet (populærvitenskap, debatt, mm))
  • 16.
    Holtstam, Dan
    et al.
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Biagioni, Cristian
    Università di Pisa, Italy.
    Hålenius, Ulf
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Brattforsite, Mn19(AsO3)12Cl2, a new arsenite mineral relatedto magnussonite, from Brattforsgruvan, Nordmark,Värmland, Sweden2021Inngår i: Mineralogy and Petrology, ISSN 0930-0708, E-ISSN 1438-1168, Vol. 115, nr 5, s. 595-609Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Brattforsite is an approved mineral (IMA2019-127), with ideal formula Mn19(AsO3)12Cl2. Associated minerals in the type specimen from the Brattfors mine, Nordmark (Värmland, Sweden) include jacobsite, alleghanyite, phlogopite, calcite anddolomite. Brattforsite, forming subhedral, mostly equant crystals up to 0.5 mm across, is orange to reddish-brown with a white streak, and translucent with a resinous to vitreous lustre. The fracture is uneven to subconchoidal, and no cleavage is observed. It is very weakly pleochroic in yellow, optically biaxial (–) with 2V = 44(5)° and has calculated mean refractive index of 1.981. Measured and calculated density values are 4.49(1) and 4.54(1) g·cm−3, respectively. Chemical analyses yields (in wt%): MgO 0.62, CaO 1.26, MnO 48.66, FeO 0.13, As2O3 46.72, Cl 2.61, H2Ocalc 0.07, O ≡ Cl –0.59, sum 99.49, corresponding to the empirical formula (Mn17.67Ca0.58Mg0.40Fe0.05)Σ18.70As12.17O35.90Cl1.90(OH)0.20, based on 38 (O + Cl + OH) atoms per formula unit. The five strongest Bragg peaks in the powder X-ray diffraction pattern are [d (Å), I (%), (hkl)]: 2.843,100, (-444)); 2.828, 99,(444); 1.731, 32, (880); 2.448, 28, (800); 1.739, 25, (088). Brattforsite is monoclinic and pseudotetragonal, space group I2/a, with unit-cell parameters a = 19.5806(7), b = 19.5763(7), c = 19.7595(7) Å, β = 90.393(3)°, V = 7573.9(5) Å3 and Z = 8. The crystal structure was solved and refined to an R1 index of 3.4% for 7445 reflections [Fo > 4σ(Fo)]. Brattforsite has the same overall structural topology as magnussonite (i.e., the species can be considered as homeotypic), but with 12 independent tetrahedrally coordinated As sites and 21 Mn sites with varying (4–8) coordination. The Mn-centered polyhedra, bonded through edge- and face-sharing, give rise to a three-dimensional framework. The (AsO3)3− groups are bonded to this framework through corner- and edge-sharing. Spectroscopic measurements (optical absorption, Raman, FTIR) carried out support the interpretation of the compositional and structural data.

    Fulltekst (pdf)
    fulltext
  • 17.
    Holtstam, Dan
    et al.
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Bindi, Luca
    University of Florence.
    Crystal structure and composition of hiärneite, Ca2Zr4Mn3+SbTiO16, and constitution of the calzirtite group2022Inngår i: Mineralogical magazine, ISSN 0026-461X, E-ISSN 1471-8022, Vol. 86, nr 2, s. 314-318Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    The crystal structure of hiärneite has been refined from single-crystal X-ray diffraction data (λ = 0.71073 Å) on type material from Långban, Värmland, Sweden. The refinement converged to R1 = 0.046 based on 1073 reflections with F2 > 4σ(F2). The tetragonal unit cell, space group I41/acd, has the parameters a = 15.2344(6) Å and c = 10.0891(6) Å with Z = 8. The mineral is isostructural with calzirtite, ideally Ca2Zr5Ti2O16, with a structural topology derived from fluorite. In hiärneite, Mn3+ is ordered at a 4- to 8-fold coordinated site (with a distorted polyhedral coordination figure), without the atom splitting encountered at the corresponding Zr-dominated site of calzirtite. The end-member formula for hiärneite is established as Ca2Zr4Mn3+SbTiO16. The calzirtite group, with calzirtite, hiärneite and tazheranite (cubic ZrO2-x), has been approved by the IMA–CNMNC.

    Fulltekst (pdf)
    fulltext
  • 18.
    Holtstam, Dan
    et al.
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Bindi, Luca
    University of Florence.
    Bonazzi, Paola
    Università degli Studi di Firenze.
    Förster, Hans-Jürgen
    Helmholtz Centre Potsdam GFZ German Research Centre for Geosciences, Section Geoenergy, 14473 Potsdam, Germany.
    Andersson, Ulf B.
    Luossavaara-Kiirunavaara AB, R&D, TG, SE-981 86 Kiruna, Sweden.
    Arrheniusite-(Ce), CaMg[(Ce7Y3)Ca5](SiO4)3(Si3B3O18)(AsO4)(BO3)F11, a new member of the vicanite group, from the Östanmossa mine, Norberg, Sweden2021Inngår i: Canadian Mineralogist, ISSN 0008-4476, E-ISSN 1499-1276, Vol. 59, s. 177-189Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Arrheniusite-(Ce) is a new mineral (IMA 2019-086) from the Östanmossa mine, one of the Bastnäs-type deposits in the Bergslagen ore region, Sweden. It occurs in a metasomatic F-rich skarn, associated with dolomite, tremolite, talc, magnetite, calcite, pyrite, dollaseite-(Ce), parisite-(Ce), bastnäsite-(Ce), fluorbritholite-(Ce) and gadolinite-(Nd). Arrheniusite-(Ce) forms anhedral, greenish-yellow translucent grains, up to 0.8 mm exceptionally. It is optically uniaxial (-), with ω = 1.750(5), ε = 1.725(5), and non-pleochroic in thin section. The calculated density is 4.78(1) g/cm3. Arrheniusite-(Ce) is trigonal, space group R3m, with unit-cell parameters a = 10.8082(3) Å, c = 27.5196(9) Å, and V = 2784.07(14) Å3 for Z = 3. The crystal structure was refined from X-ray diffraction data to R1 = 3.85 for 2286 observed reflections [Fo > 4σ(Fo)]. The empirical formula for the fragment used for the structural study, based on EPMA data and results from the structure refinement, is (Ca0.65As3+0.35)Σ1(Mg0.57Fe2+0.30As5+0.10Al0.03)Σ1[(Ce2.24Nd2.13La0.86Gd0.74Sm0.71Pr0.37)Σ7.05(Y2.76Dy0.26Er0.11Tb0.08Tm0.01Ho0.04Yb0.01)Σ3.27Ca4.14]Σ14.46(SiO4)3[(Si3.26B2.74)Σ6O17.31F0.69][(As5+0.65Si0.22P0.13)Σ1O4](B0.77O3)F11; the ideal formula obtained is CaMg[(Ce7Y3)Ca5](SiO4)3(Si3B3O18)(AsO4)(BO3)F11. Arrheniusite-(Ce) belongs to the vicanite group of minerals, and is distinct from other isostructural members mainly by having a Mg-dominant, octahedrally coordinated site (M6); it can be considered as a Mg-As analog to hundholmenite-(Y). The three-fold coordinated T5 site is partly occupied by B, like in laptevite-(Ce) and vicanite-(Ce). The mineral name honors C.A. Arrhenius (1757–1824), a Swedish officer and chemist, who first discovered gadolinite-(Y), from the famous Ytterby pegmatite quarry.

  • 19.
    Holtstam, Dan
    et al.
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Bindi, Luca
    University of Florence.
    Förster, Hans-Jürgen
    GFZ German Research Centre for Geosciences .
    Karlsson, Andreas
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Gatedal, Kjell
    Garpenbergite, Mn6□As5+Sb5+O10(OH)2, a new mineral related to manganostibite, from the Garpenberg Zn–Pb–Ag deposit, Sweden2022Inngår i: Mineralogical magazine, ISSN 0026-461X, E-ISSN 1471-8022, Vol. 86, nr 1, s. 1-8Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Garpenbergite is a new mineral (IMA2020-099) from the Garpenberg Norra mine, Hedemora, Dalarna, Sweden. It occurs with carlfrancisite and minor stibarsen, paradocrasite and filipstadite in a fractured skarn matrix of granular jacobsite, alleghanyite, kutnohorite and dolomite. Crystals are short-prismatic, up to 1.5 mm in length. They have a blackish to greyish brown colour, and are lustrous semi-opaque, with brown streak. Garpenbergite is brittle, with an uneven to subconchoidal fracture. Cleavage is distinct on {010}. Hardness ≈ 5 (Mohs) and VHN100 = 650(40). Dcalc = 4.47(1) g⋅cm−3 , overall ncalc = 1.85. Maximum specular reflectance values (%) obtained are 9.2 (470 nm), 9.1 (546 nm), 9.0 (589 nm) and 8.9 (650 nm). The empirical chemical formula of garpenbergite, based on electron microprobe data, is (Mn2+3.97Mg1.48Mn3+0.26Zn0.296.00(As0.89Fe3+0.04Mn3+0.06Si0.01)Σ1.00(Sb0.98Fe0.02)Σ1.00O10[(OH)1.99Cl0.012.00. The five strongest Bragg peaks in the powder X-ray diffraction pattern [d, Å(I, %) (hkl)] are 3.05 (30) (002), 2.665 (100) (161), 2.616 (40) (301), 2.586 (25) (251) and 1.545 (45) (462). The orthorhombic unit-cell dimensions (in Å) are a = 8.6790(9), b = 18.9057(19) and c = 6.1066(6), with V = 1001.99(18) Å3 for Z = 4. The crystal structure was refined from single-crystal X-ray diffraction data in the space-group Ibmm to R1 = 3.7% for 957 reflections. Garpenbergite, ideally Mn6As5+Sb5+O10(OH)2, is isostructural with manganostibite, Mn7AsSbO12, but possesses a cation vacancy (□) at an octahedrally coordinated structural site; the two minerals are thus related by the exchange Mn2+ + 2O2– → □ + 2(OH) . The presence of hydroxyl groups is supported by vibration bands at 3647 and 3622 cm−1 in the Raman spectrum of garpenbergite, and by bond-valence considerations.

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  • 20.
    Holtstam, Dan
    et al.
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Bindi, Luca
    Università di Firenze, Italy.
    Hålenius, Ulf
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Andersson, Ulf Bertil
    Luossavaara-Kiirunavaara AB, Kiruna, Sweden.
    Delhuyarite-(Ce) – Ce4Mg(Fe3+2W)□(Si2O7)2O6(OH)2 – a new mineral of the chevkinite group, from the Nya Bastnäs Fe–Cu–REE deposit, Sweden2017Inngår i: European journal of mineralogy, ISSN 0935-1221, E-ISSN 1617-4011, Vol. 29, nr 5, s. 897-905Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Delhuyarite-(Ce) is a new mineral (IMA no. 2016-091) with ideal formula Ce4Mg(Fe3+2W)□(Si2O7)2O6(OH)2. It is named after Juan and Fausto de Elhuyar (Delhuyar), chemists and metallurgists, who in 1783 isolated tungsten metal for the first time.  Associated minerals in the only known sample, from the Nya Bastnäs Fe–Cu–REE deposit (Västmanland, Sweden), include cerite-(Ce), tremolite‒actinolite, percleveite-(Ce), bastnäsite-(Ce), ferriallanite-(Ce), törnebohmite-(Ce), magnetite, chalcopyrite, quartz and scheelite. Delhuyarite-(Ce), which forms subhedral crystals up to 0.3mm long, is brown–black with a dark brown streak and translucent with an adamantine lustre. It is pleochroic in black to rust red and optically biaxial (-). Calculated density and mean refractive index are 5.20 g·cm-3 and 1.94, respectively. Chemical analyses (electron microprobe) gave (in wt%) La2O3 14.58, Ce2O3 23.29, Pr2O1.89, Nd2O3 6.13, Sm2O3 0.74, Gd2O3 0.37, Dy2O3 0.03, Er2O3 0.04, Yb2O3 0.12, Y2O3 0.22, CaO 0.76, Fe2O3 12.86, MgO 2.43, Al2O3 0.73, SiO2 18.16, TiO2 0.09, WO3 15.53, H2Ocalc 1.33, F 0.05, Cl 0.03, O=(F, Cl) 0.03, sum 99.35, corresponding to an empirical formula: (Ce1.89La1.19Nd0.48Pr0.15Sm0.06Gd0.03Y0.03Ca0.18)Σ4.01(Fe3+2.14W0.89Mg0.80Al0.19Ti0.02)Σ4.04Si4.01O20(OH1.96F0.04)Σ2, based on 22 O atoms per formula unit (apfu). The presence of H2O is confirmed by IR-spectroscopy, from a strong absorption band at 3495 cm-1. Delhuyarite-(Ce) is monoclinic, space group C2/m, with unit-cell parameters a =13.6020(6)Å, b = 5.7445(3)Å, c = 10.9996(5)Å, β = 100.721(4)°, V = 844.47 (6)Å3 and Z = 2 (data for natural crystal). The crystal structure was refined to an R1 index of 3.9% (natural crystal) and 1.8% (annealed). Delhuyarite-(Ce) has the same structural topology as chevkinite subgroup minerals, e.g. chevkinite-(Ce). It is the only mineral of the group with a significant content of W6+ = 0.89 apfu. In delhuyarite-(Ce), Mg is dominant at the M1 site as in polyakovite-(Ce); the composition of the M2, M3 and M4 sites is [(Fe3+2W)□], with M2 being 50% vacant.

  • 21.
    Holtstam, Dan
    et al.
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Bindi, Luca
    Università di Firenze, Italy.
    Hålenius, Ulf
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Kolitsch, Uwe
    Naturhistorisches Museum, Wien, Austria.
    Mansfeld, Joakim
    Stockholm University, Sweden.
    Ulfanderssonite-(Ce), a new Cl-bearing REE silicate mineral species from the Malmkärra mine, Norberg, Sweden2017Inngår i: European journal of mineralogy, ISSN 0935-1221, E-ISSN 1617-4011, Vol. 29, nr 6, s. 1015-1026Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Ulfanderssonite-(Ce) is a new mineral (IMA 2016-107) from the long-abandoned Malmkärra iron mine, one of the Bastnäs-type Fe-rare earth element (REE) deposits in the Bergslagen ore region, central Sweden. It is named for Ulf B. Andersson, a Swedish geologist and petrologist. In the type specimen, the mineral occurs with västmanlandite-(Ce), bastnäsite-(Ce), phlogopite, talc, magnetite, pyrite, fluorbritholite-(Ce) and scheelite. Ulfanderssonite-(Ce) forms pinkish, translucent subhedral grains, 100–300 mm, in aggregates up to 2 mm. Fracture is uneven, and there is an indistinct cleavage parallel (001). Mohs' hardness is 5−6, dcalc= 4.97 g·cm-3. Optically, ulfanderssonite-(Ce) is nonpleochroic, biaxial negative, with 2Vmeas =55° and ncalc=1.82. The ideal composition is Ce15CaMg2(SiO4)10(SiO3OH)(OH,F)5Cl3. EMP and LA-ICP-MS chemical analyses yielded (in wt%) La2O3 11.87, Ce2O3 30.98, Pr2O3 3.99, Nd2O3 17.14, Sm2O3 2.81, Eu2O3 0.18, Gd2O3 1.15, Dy2O3 0.30, Tb2O3 0.10, Y2O3 1.11, CaO 2.26, FeO 0.02, MgO 1.97, P2O5 0.08 SiO2 19.13, H2Ocalc 1.07, F 1.09, Cl 2.89, O=(F, Cl) -1.10, sum 97.04. The five strongest powder X-ray diffraction lines are [I (%) dobs(Å) (hkl)]: 100 2.948 (-421), 47 2.923 (204), 32 2.660 (-225), 26 3.524 (40-1), 25 1.7601 (6-23). Ulfanderssonite-(Ce) is monoclinic, Cm, with a =14.1403(8), b = 10.7430(7), c = 15.498(1) Å, β = 106.615(6)° and V = 2256.0(2) Å3 for Z = 2. The crystal structure has been solved by direct methods and refined to R1 = 2.97% for 5280 observed reflections. It consists of a regular alternation of two layers, designated A and B, along the c-axis: A (ca. 9 Å thickness), with composition [(Ce8Ca)MgSiO22(OH,F)4]8+, and B (ca. 6.5 Å), with composition [Ce7Mg­Si4O21(OH,F)2Cl3]8-; the A layer is topologically and chemically closely related to cerite-(Ce). A FTIR spectrum shows strong absorption in the region 2850−3650 cm-1, related to the presence of O-H stretching bands. Ulfanderssonite-(Ce) is interpreted as a primary mineral at the deposit, along with the more common fluorbritholite-(Ce), formed by a magmatic-hydrothermal fluid with REE, Si, F and Cl ion complexes reacting with dolomite marble. The presence of ulfanderssonite-(Ce) is direct evidence of a Cl-rich mineral-forming aqueous solution, normally not reflected in the composition of skarn minerals in Bastnäs-type deposits.

  • 22.
    Holtstam, Dan
    et al.
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Bindi, Luca
    University of Florence.
    Karlsson, Andreas
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Langhof, Jörgen
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Zack, Thomas
    Göteborgs universitet.
    Bonazzi, Paola
    Università degli Studi di Firenze.
    Persson, Anders
    Kesebolite-(Ce), CeCa2Mn(AsO4)[SiO3]3, a new REE-bearing arsenosilicate mineral from the Kesebol mine, Åmål, Västra Götaland, Sweden2020Inngår i: Minerals, E-ISSN 2075-163X, Vol. 10, nr 385, s. 1-14Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Kesebolite-(Ce), ideal formula CeCa2Mn(AsO4)[SiO3]3, is a new mineral (IMA No. 2019-097) recovered from mine dumps at the Kesebol Mn-(Fe-Cu) deposit in Västra Götaland, Sweden. It occurs with rhodonite, baryte, quartz, calcite, talc, andradite, rhodochrosite, K-feldspar, hematite,gasparite-(Ce), chernovite-(Y) and ferriakasakaite-(Ce). It forms mostly euhedral crystals, with lengthwise striation. The mineral is dark grayish-brown to brown, translucent, with light brown streak. It is optically biaxial (+), with weak pleochroism, and ncalc = 1.74. H = 5–6 and VHN100 = 825. Fair cleavage is observed on {100}. The calculated density is 3.998(5) g/cm-3. Kesebolite-(Ce) ismonoclinic, P21/c, with unit-cell parameters from X-ray single-crystal diffraction data: a = 6.7382(3), b = 13.0368(6), c = 12.0958(6) Å, beta = 98.578(2) degr., and V = 1050.66(9) Å3, with Z = 4. Strongest Braggpeaks in the X-ray powder pattern are: [I(%), d(Å) (hkl)] 100, 3.114 (20-2); 92, 2.924 (140); 84, 3.138(041); 72, 2.908 (014); 57, 3.228 (210); 48, 2.856 (042); 48, 3.002 (132). The unique crystal structure wassolved and refined to R1 = 4.6%. It consists of 6-periodic single silicate chains along (001); these are interconnected to infinite (010) strings of alternating, corner-sharing MnO6 and AsO4 polyhedra, altogether forming a trellis-like framework parallel to (100).

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  • 23.
    Holtstam, Dan
    et al.
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Bindi, Luca
    University of Florence.
    Karlsson, Andreas
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Söderhielm, Johan
    Sveriges Geologiska Undersökning.
    Zetterqvist, Anders
    Zetterqvist Geokonsult AB, Bromma, Sweden.
    Muonionalustaite, Ni3(OH)4Cl2·4H2O, a new mineral formed by terrestrial weathering of the Muonionalusta iron (IVA) meteorite, Pajala, Norrbotten, Sweden2021Inngår i: GFF, ISSN 1103-5897, E-ISSN 2000-0863, Vol. 143, nr 1, s. 1-7Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Muonionalustaite, ideally Ni3(OH)4Cl2·4H2O, is a new mineral species (IMA 2020-010), found as a terrestrial weathering product of the Muonionalusta iron meteorite, in a fragment excavated 1.5 km NE of Lake Kitkiöjärvi. Muonionalustaite occurs in cavities of corrosion crust, associated with taenite, goethite, maghemite, amorphous Fe-Ni oxy-hydroxides and soil mineral particles. The mineral is green in colour and transparent. It occurs as lath-like crystals up to ca. 5 μm, elongated along [010] and flattened on {001}, forming aggregates and thin crusts. The calculated density and overall refractive index are 2.67(1) g·cm-3 and 1.68, respectively. An empirical formula from point analyses is (Ni2.88Fe0.02S0.02Al0.01Si0.012.94(OH3.73Cl2.276.00·4H2O. The crystal structure was refined in the space-group C2/m from powder X-ray diffraction data to RBragg = 3.55%. The monoclinic unit-cell parameters are a = 15.018(3) Å, b = 3.1490(6) Å, c = 10.502(3) Å, β = 101.535(15)º and V = 486.62(19) Å3 for Z = 2. Muonionalustaite is isostructural with the synthetic compounds Ni3(OH)3.9Cl2.1·4H2O and Mg3(OH)4Cl2·4H2O. The strongest X-ray diffraction lines are [I(%), d(Å), hkl]: 100, 10.30, 001; 67, 5.49, 201; 31, 3.868, 202; 30, 7.36, 200 and 25, 2.409, 60-2. Raman spectra show prominent bands at 3624, 3612, 3571 and 3507 cm-1, respectively, related to O–H-stretching vibrations of OH- groups, and in the region 450–530 cm-1 representing metal–O(H) vibration modes.

  • 24.
    Holtstam, Dan
    et al.
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Casey, Patrick
    Sveriges Geologiska Undersökning.
    Bindi, Luca
    University of Florence.
    Förster, Hans-Jürgen
    Karlsson, Andreas
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Appelt, Oona
    Fluorbritholite-(Nd), Ca2Nd3(SiO4)3F, a new and key mineral for neodymium sequestration in REE skarns2023Inngår i: Mineralogical magazine, ISSN 0026-461X, E-ISSN 1471-8022, Vol. 87, nr 5, s. 731-737Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Fluorbritholite-(Nd), ideally Ca2Nd3(SiO4)3F, is an approved mineral (IMA 2023-001) and constitutes a new member of the britholite group of the apatite supergroup. It occurs in skarn from the Malmkärra iron mine, Norberg, Västmanland (one of the Bastnäs-type deposits in Sweden), associated with calcite, dolomite, magnetite, lizardite, talc, fluorite, baryte, scheelite, gadolinite-(Nd) and other REE minerals. Fluorbritholite-(Nd) forms anhedral and small grains, rarely up to 250 µm across. They are brownish pink, transparent with a vitreous to greasy luster. The mineral is brittle, with an uneven or subconchoidal fracture, and lacks a cleavage. In thin section, the mineral is nonpleochroic, uniaxial (-). Dcalc = 4.92(1) g·cm-3 and ncalc = 1.795. The empirical chemical formula from electron microprobe (WDS) point analyses is (Ca1.62Nd0.97Ce0.83Y0.52Sm0.30Gd0.23Pr0.17La0.16Dy0.11Er0.03Tb0.03Ho0.01Yb0.01)Σ4.99(Si2.92P0.08As0.013.01O12.00[O0.48F0.26(OH)0.14Cl0.10Br0.02]Σ1.00. The crystal structure of fluorbritholite-(Nd) was refined from single-crystal X-ray diffraction data to R1= 0.043 for 704 unique reflections. It belongs to the hexagonal system, space group P63/m, with unit cell parameters a = 9.5994(3), c = 6.9892(4) Å, V = 557.76(5) Å3 for Z = 2. Fluorbritholite-(Nd) and other britholite-group minerals are a major sink for neodymium in REE-bearing skarns of Bastnäs type. 

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  • 25.
    Holtstam, Dan
    et al.
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Cámara, Fernando
    Università degli Studi di Milano,.
    Jagoite revisited2022Inngår i: Abstracts, International Mineralogical Association, 23rd General meeting, Lyon, 2022, Vol. 3, s. 34-34Konferansepaper (Annet vitenskapelig)
    Abstract [en]

    Jagoite, nominal formula Pb11Fe5Si12O41Cl3, was described in 1957 by Blix et al. It is only known from the Långban and Pajsberg Fe-Mn deposits, in the Filipstad district, Värmland, Sweden. The crystal structure was solved by Mellini & Merlino in 1981. We have reinvestigated the mineral in samples from both localities. The crystal structure was refined (R1 = 1.2% for 2090 reflections with Fo > 4σ(Fo)) from type material and the original structural model is essentially confirmed. Chemical analyses indicate that Al3+ could substitute for Fe3+ in jagoite, up to 2.3 wt. % Al2O3; Mn and Zn is also present in some samples (up to 1.7 wt.% Mn2O3 and 1.2 wt.% ZnO, respectively). Two tetrahedrally coordinated sites have unusually short bonds, which may indicate substitution of Si by a small cation like B3+. Pb and Cl show stable concentration values and jagoite is essentially anhydrous. 57Fe Mössbauer data have been collected from a powder absorber. The hyperfine parameters are consistent with Fe being present only in trivalent form (high spin), and distributed over a relatively regular 6-coordinated site and distorted 4-coordinated sites. Distinct Raman bands appear at 183, 222, 340, 524, 635, 680, 860, 885, 925, 952, 985 and 1050 cm-1. Jagoite occurs in a skarn assemblage with andradite, diopside, hematite, quartz, together with the Pb silicates alamosite, barysilite, jagoite, joesmithite, melanotekite, nasonite and yangite. Jagoite is the mineral most susceptible to hydrothermal alteration in this association, forming new, poorly known phases in the system CaO-PbO-SiO2-H2O-Cl2.

  • 26.
    Holtstam, Dan
    et al.
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Cámara, Fernando
    Università degli Studi di Milano,.
    Karlsson, Andreas
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Instalment of the margarosanite group, and data on walstromite–margarosanite solid solutions from the Jakobsberg Mn–Fe deposit, Värmland, Sweden2021Inngår i: Mineralogical magazine, ISSN 0026-461X, E-ISSN 1471-8022, Vol. 85, s. 224-232Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    The margarosanite group (now officially confirmed by IMA-CNMNC) consists of triclinic Ca-(Ba, Pb) cyclosilicates with three-membered [Si3O9]6- rings (3R), with the general formula AB2Si3O9, where A = Pb, Ba, Ca and B = Ca. A closest-packed arrangement of O atoms parallel to (101) hosts Si and B cations in interstitial sites in alternating layers. The 3R layer has three independent Si sites in each ring. Divalent cations occupy three independent sites: Ca in B occupies two nonequivalent sites, Ca1 (8-fold coordinated), and Ca2 (6-fold coordinated). A (=Ca2) is occupied by Pb2+ (or Ba2+) in 6+4 coordination, or 6+1 when occupied by Ca; this third site occurs within the 3R-layer in a peripheral position. Three minerals belong to this group: margarosanite (ideally PbCa2Si3O9), walstromite (BaCa2Si3O9) and breyite (CaCa2Si3O9). So far, no solid solutions involving the Ca1 and Ca2 sites have been described. Therefore, root names depend on the composition of the Ca3 site only. Isomorphic replacement at the Ca3 sites has been noted. We here report data on a skarn sample from the Jakobsberg Mn-Fe oxide deposit, in Värmland (Sweden), representing intermediate compositions on the walstromite-margarosanite binary, in the range ca. 50–70% mol.% BaCa2Si3O9. The plumbian walstromite is closely associated with celsian, phlogopite, andradite, vesuvianite, diopside and nasonite. A crystal-structure refinement (R1 = 4.8%) confirmed the structure type, and showed that the Ca3 (Ba, Pb) site is split into two positions separated by 0.39 Å, with the Ba atoms found slightly more peripheral to the 3R-layers.

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  • 27.
    Holtstam, Dan
    et al.
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Cámara, Fernando
    Università degli Studi di Milano.
    Karlsson, Andreas
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Langhofite, Pb2(OH)[WO4(OH)], a new mineral from Långban, Sweden.2020Inngår i: Mineralogical magazine, ISSN 0026-461X, E-ISSN 1471-8022, Vol. 84, s. 381-389Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Langhofite, ideally Pb2(OH)[WO4(OH)], is a new mineral from the Långban mine, Värmland, Sweden. The mineral and its name were approved by the International Mineralogical Association Commission on New Minerals, Nomenclature and Classification (IMA2019-005). It occurs in a small vug in hematite–pyroxene skarn associated with calcite, baryte, fluorapatite, mimetite and minor sulfide minerals. Langhofite is triclinic, space group P1, and unit-cell parameters a = 6.6154(1) Å, b = 7.0766(1) Å, c = 7.3296(1) Å, α = 118.175(2)°,β = 94.451(1)°, γ = 101.146(1)° and V = 291.06(1) Å3 for Z = 2. The seven strongest Bragg peaks from powder X-ray diffractometry are[dobs, Å (I )(hkl)]: 6.04(24)(010), 3.26(22)(11-2), 3.181(19)(200), 3.079(24)(1-12), 3.016(100)(020), 2.054(20)(3-11) and 2.050(18)(13-2). Langhofite occurs as euhedral crystals up to 4 mm, elongated along the a axis, with lengthwise striation. Mohs hardness is ca. 2½,based on VHN25 data obtained in the range 130–192. The mineral is brittle, with perfect {010} and {100} cleavages. The calculated density based on the ideal formula is 7.95(1) g⋅cm–3. Langhofite is colourless to white (non-pleochroic) and transparent, with a white streakand adamantine lustre. Reflectance curves show normal dispersion, with maximum values 15.7–13.4% within 400–700 nm. Electron microprobe analyses yield only the metals Pb and W above the detection level. The presence of OH-groups is demonstrated with vibration spectroscopy, from band maxima present at ∼3470 and 3330 cm–1. A distinct Raman peak at ca. 862 cm–1 is related to symmetricW–oxygen stretching vibrations. The crystal structure is novel and was refined to R = 1.6%. It contains [W2O8(OH)2]6– edge-sharingdimers (with highly distorted WO6-octahedra) forming chains along [101] with [(OH)2Pb4]6+ dimers formed by (OH)Pb3 triangles. Chains configure (010) layers linked along [010] by long and weak Pb–O bonds, thus explaining the observed perfect cleavage on{010}. The mineral is named for curator Jörgen Langhof (b. 1965), who collected the discovery sample.

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  • 28.
    Holtstam, Dan
    et al.
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Cámara, Fernando
    Università degli Studi di Milano,.
    Karlsson, Andreas
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Skogby, Henrik
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Zack, Thomas
    Göteborgs universitet.
    Ferri-taramite, a new member of the amphibole supergroup, from the Jakobsberg Mn–Fe deposit, Värmland, Sweden2022Inngår i: European journal of mineralogy, ISSN 0935-1221, E-ISSN 1617-4011, Vol. 34, nr 5, s. 451-462Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Ferri-taramite (IMA CNMNC 2021-046), ideally ANaB(CaNa)C(Mg3Fe)T(Si6Al2)O22W(OH)2, occurs in skarn from the Jakobsberg manganese mine, Värmland, Sweden. Associated minerals are celsian, phlogopite, aegirine-augite, andradite, hancockite, melanotekite, microcline (var. hyalophane), calcite, baryte, prehnite, macedonite and oxyplumboroméite. Conditions of formation, close to peak metamorphism (at circa 650∘C and 0.4 GPa), include silica undersaturation, a slightly peralkaline character and relatively high oxygen fugacities. Ferri-taramite forms poikiloblastic crystals up to 5 mm and is dark brownish black with a yellowish grey streak. The amphibole is brittle with an uneven to splintery fracture. Cleavage parallel to {110} is good. Hardness (Mohs) is ∼ 6, and Dcalc=3.227(5) g cm−3. Holotype ferri-taramite has the experimental unit formula A(Na0.79K0.16Pb0.01)Σ0.96B(Ca1.26Na0.72Mn0.02)Σ2C(Mg2.66Mn2+0.58Fe2+0.16Zn0.02Fe3+1.26 Al0.26Ti0.06)Σ5T(Al1.86Si6.14)Σ8O22W(OH)2, based on chemical analyses (EDS, laser-ablation ICP-MS) and spectroscopic (Mössbauer, infrared) and single-crystal X-ray diffraction data. The mineral is optically biaxial (–), with α=1.670(5), β=1.680(5) and γ=1.685(5) in white light and 2Vmeas=70(10)∘ and 2Vcalc=70.2∘. Ferri-taramite is distinctly pleochroic in transmitted light, with X pale yellow, Y dark brown, Z yellowish brown and absorption Y>Z>X. The eight strongest reflections in the X-ray powder pattern (d values (in Å), Irel, hkl) are 8.44, 60, 110; 3.392, 25, 131; 3.281, 39, 240; 3.140, 100, 310; 2.816, 45, 330; 2.7104, 38, 151; 1.3654, 26, 461; and 1.4451, 33, -661. Refined unit-cell parameters from single-crystal diffraction data are a=9.89596(13), b=18.015(2), c=5.32164(7) Å, β=105.003(13)∘ and V=916.38(2) Å3 for Z=2. Refinement of the crystal structure yielded R=2.26 % for 2722 reflections with Io>2σ(I). The Mn2+ and Fe2+ ions show preference for the M1 and M3 octahedrally coordinated sites, whereas Fe3+ is strongly ordered at M2. The A-group cations, K and Na, are split over two subsites, A(m) and A(2), respectively.

    Fulltekst (pdf)
    fulltext
  • 29.
    Holtstam, Dan
    et al.
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Cámara, Fernando
    Università degli Studi di Milano.
    Skogby, Henrik
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Karlsson, Andreas
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Hjalmarite, a new Na-Mn member of the amphibole supergroup, from Mn skarn in the Långban deposit, Värmland, Sweden.2019Inngår i: European journal of mineralogy, ISSN 0935-1221, E-ISSN 1617-4011, Vol. 31, s. 565-574Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Hjalmarite, ideally ANaB(NaMn)CMg5TSi8O22W(OH)2, is a new root-name member of the amphibole supergroup, discovered in skarn from the Långban Fe-Mn-(Ba-As-Pb-Sb-Be-B) deposit, Filipstad, Värmland, Sweden (IMA-CNMNC 2017-070). It occurs closely associated with mainly rhodonite and quartz. It is grayish white with vitreous luster and non-fluorescent. The crystals are up to 5 mm in length and display splintery fracture and perfect cleavage along {110}. Hjalmarite is colorless (non-pleochroic) in thin section and optically biaxial (-), with α = 1.620(5), β = 1.630(5), γ = 1.640(5). The calculated density is 3.12 Mg/m3. Average VHN100 is 782, corresponding to circa 5½ Mohs. An empirical formula, derived from EPMA analyses in combination with crystal structure refinements, is (Na0.84K0.16)Σ1(Na1.01Mn0.55Ca0.43Sr0.01) Σ2(Mg3.83Mn1.16Al0.01) Σ5(Si7.99Al0.01) Σ8O22(OH1.92F0.08)Σ2. An infra-red spectrum of hjalmarite shows distinct absorption bands at 3673 cm-1 and 3731 cm-1 polarized in the α direction. The eight strongest Bragg peaks in the powder X-ray diffraction pattern are [d (Å), I (%), (hkl)]: 3.164, 100, (310); 2.837, 50, (330); 8.50, 44, (110); 3.302; 40, (240); 1.670, 34, (461); 1.448, 32, (-661); 2.727, 30, (151); 2.183, 18 (261).

    Single-crystal X-ray diffraction data were collected at 298 K and 180 K. The crystal structure was refined in space group C2/m to R1=2.6% [I>2(I)], with observed unit-cell parameters a = 9.9113(3), b = 18.1361(4), c = 5.2831(5) Å, β=103.658(5)° and V = 922.80(9) Å3 at ambient temperature. The A and M(4) sites split into A(m) (K+), A(2) (Na+), and M(4’) (Mn2+) subsites, respectively. Among the octahedrally coordinated C group cations, Mn2+ orders strongly at the M(2) site. No significant violation of C2/m symmetry or change in the structure topology is detected at low temperature (R1=2.1%). The hjalmarite-bearing skarn formed at peak regional metamorphism, T  ≥ 600°C, at conditions of high SiO2 activity and relatively low oxygen fugacity. The mineral name honors the Swedish geologist and mineralogist S.A. Hjalmar Sjögren (1856–1922).

  • 30.
    Holtstam, Dan
    et al.
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Cámara, Fernando
    Università degli Studi di Milano.
    Skogby, Henrik
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Karlsson, Andreas
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Langhof, Jörgen
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Recognition and approval of potassic-richerite, an amphibole supergroup mineral, from the Pajsberg mines, Filipstad, Sweden.2019Inngår i: Mineralogy and Petrology, ISSN 0930-0708, E-ISSN 1438-1168, Vol. 113, s. 7-16Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Potassic-richterite, ideally AKB(NaCa)CMg5TSi8O22W(OH)2, is recognized as a valid member of the amphibole supergroup (IMA CNMNC 2017–102). Type material is from the Pajsberg Mn-Fe ore field, Filipstad, Värmland, Sweden, where the mineral occurs in a Mn-rich skarn, closely associated with mainly phlogopite, jacobsite and tephroite. The megascopic colour is straw yellow to grayish brown and the luster vitreous. The nearly anhedral crystals, up to 4 mm in length, are pale yellow (non-pleochroic) in thin section andoptically biaxial (−), with α = 1.615(5), β = 1.625(5), γ = 1.635(5). The calculated density is 3.07 g·cm−1. VHN100 is in the range 610–946. Cleavage is perfect along {110}. EPMA analysis in combination with Mössbauer and infrared spectroscopy yields the empirical formula (K0.61Na0.30Pb0.020.93(Na1.14Ca0.79Mn0.07)Σ2(Mg4.31Mn0.47Fe3+0.20)Σ5(Si7.95Al0.04Fe3+0.01)Σ8O22(OH1.82F0.18)Σ2 for a fragmentused for collection of single-crystal X-ray diffraction data. The infra-red spectra show absorption bands at 3672 cm−1 and 3736 cm−1 for the α direction. The crystal structure was refined in space group C2/m to R1=3.6% [I >2σ(I)], with resulting cellparameters a = 9.9977(3) Å, b = 18.0409(4) Å, c = 5.2794(2) Å, γ = 104.465(4)°, V = 922.05(5) Å3 and Z=2. The A and M(4) sites split into A(m) (K+), A(2/m) (Na+), A(2) (Pb2+), and M(4′) (Mn2+) subsites, respectively. The remaining Mn2+ is strongly ordered at theoctahedrally coordinated M(2) site, possibly together with most of Fe3+. The skarn bearing potassic-richterite formed at peak metamorphism, under conditions of low SiO2 and Al2O3 activities and relatively high oxygen fugacities.

  • 31.
    Holtstam, Dan
    et al.
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Hålenius, Ulf
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Nomenclature of the magnetoplumbite group2020Inngår i: Mineralogical magazine, ISSN 0026-461X, E-ISSN 1471-8022, Vol. 84, nr 3, s. 376-380Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    A nomenclature classification scheme has been approved by IMA-CNMNC for the magnetoplumbite group, with the general formula A[B12]O19. The classification on the highest hierarchical level is decided by the dominant metal at the 12-coordinated A sites, at present leading to the magnetoplumbite (A = Pb), hawthorneite (A = Ba) and hibonite (A = Ca) subgroups. Two species remain ungrouped. Most cations, with valencies from 2+ to 5+, show strong order over the five crystallographic B sites present in the crystal structure, which forms the basis for the definition of different mineral species. A new name, chihuahuaite, is introduced and replaces hibonite-(Fe).

    Fulltekst (pdf)
    fulltext
  • 32.
    Holtstam, Dan
    et al.
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Karlsson, Andreas
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    An unusual mineral assemblage of Pb silicates2022Inngår i: Geological Society of Sweden, 150 year anniversary meeting, Uppsala, August 17–19 2022, Abstract volume., Uppsala, 2022, Vol. 1, s. 356-357Konferansepaper (Fagfellevurdert)
    Abstract [en]

    Rare assemblages of Pb silicates, from skarn in the Långban and Pajsbergs mines, Värmland, Sweden, have been investigated. Minerals observed are alamosite, barysilite, jagoite, joesmithite, melanotekite, nasonite and yangite, together with common metamorphic skarn components like andradite, diopside, hematite and quartz. Jagoite likely formed from primary melanotekite and quartz under the influence of a fluid with high Cl activity. Jagoite is prone to hydrothermal alteration, producing unidentified phases in the system CaO–PbO–SiO2–H2O–(±Cl2).

  • 33.
    Holtstam, Dan
    et al.
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Söderhielm, Johan
    Sveriges Geologiska Undersökning.
    An 18th century find of an erratic lazulite-andalusite-quartz boulder in Södermanland, Sweden, and its implications2019Inngår i: GFF, ISSN 1103-5897, E-ISSN 2000-0863, Vol. 141, nr 3, s. 216-221Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    At some point in the 1750s, a jeweller-apprentice by the name Jacob Hässelgren found an erratic bouldernext to the Eskilstuna country road in the neighbourhood of Ärla in Södermanland. It contained a deep bluemass of lazulite, at the time an unknown mineral. Pieces of the find eventually reached Daniel Tilas, TorbernBergman and Axel Fredrik Cronstedt ˗ renowned natural scientists in Sweden ˗ but no detailed studies of thematerial seem to have been carried out by them. Two fragments of the original boulder are still preserved,and a recent examination shows them to consist of mainly lazulite, andalusite, quartz, pyrophyllite, augeliteand svanbergite. The average composition of lazulite is Mg0.700Fe2+0.261Mn0.003Al1.954Fe3+0.017 P2.031O8(OH)2.The mineral assemblage is characteristic of known occurrences of phosphate-Al silicate-quartz appearingalong the Protogine Zone in southern Sweden. Transportation of the boulder from its source rock, likely tobe located somewhere along the Protogine Zone, ought to have occurred in connection with the developmentof the Fennoscandian ice sheet during the final Weichselian deglaciation, and the material waspossibly discharged from floating ice on the Yoldia Sea.

  • 34.
    Karlsson, Andreas
    et al.
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Holtstam, Dan
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Bindi, Luca
    Dipartimento di Scienze della Terra, Università degli Studi di Firenze.
    Bonazzi, Poala
    Dipartimento di Scienze della Terra, Università degli Studi di Firenze.
    Konrad-Schmolke, Matthias
    Department of Earth Sciences, University of Gothenburg.
    Adding complexity to the garnet supergroup: monteneveite, Ca3Sb5+2(Fe3+2Fe2+)O12, a new mineral from the Monteneve mine, Bolzano Province, Italy2020Inngår i: European journal of mineralogy, ISSN 0935-1221, E-ISSN 1617-4011, Vol. 32, nr 1, s. 77-87Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Monteneveite, ideally Ca3Sb5+2(Fe3+2Fe2+)O12, is a new member of the garnet supergroup (IMA2018-060). The mineral was discovered in a small specimen belonging to the Swedish Museum of Natural History coming from the now abandoned Monteneve Pb–Zn mine in Passiria Valley, Bolzano Province, Alto Adige (South Tyrol), Italy. The specimen consists of mainly magnetite, sphalerite, tetrahedrite-(Fe) and oxycalcioroméite. Monteneveite occurs as black, subhedral crystals with adamantine lustre. They are equidimensionaland up to 400 μm in size, with a subconchoidal fracture. Monteneveite is opaque, grey in reflected light,and isotropic under crossed polars. Measured reflectance values (%) at the four COM wavelengths are 12.6 (470 nm), 12.0 (546 nm), 11.6 (589 nm) and 11.4 (650 nm). The Vickers hardness (VHN100) is 1141 kg mm-2, corresponding to H = 6.5–7, and the calculated density is 4.72(1) g cm-3. A mean of 10 electron microprobe analyses gave (wt %) CaO 23.67, FeO 3.75, Fe2O3 29.54, Sb2O5 39.81, SnO2 2.22, ZnO 2.29, MgO 0.15, MnO 0.03 and CoO 0.03. The crystal chemical formula calculated on the basis of a total of eight cations and 12 anions, and taking into account the available structural and spectroscopic data, is (Ca2.97Mg0.03)Σ=3.00(Sb5+1.73Sn4+0.10Fe3+0.17)Σ=2.00(Fe3+2:43Fe2+0.37Zn0.20)Σ=3.00O12. The most significant chemical variations encounteredin the sample are related to a substitution of the type YSn4+ + ZFe3+  YSb5+ + ZFe2+. Mössbauer data obtained at RT and 77K indicate the presence of tetrahedrally coordinated Fe2+. Raman spectroscopy demonstrates that there is no measurable hydrogarnet component in monteneveite. The six strongest Bragg peaks in the powder X-ray diffraction pattern are [d (Å), I (%), (hkl)]: 4.45, 100, (220); 3.147, 60, (400); 2.814, 40, (420); 2.571, 80, (422); 1.993, 40, (620); 1.683, 60, (642). Monteneveite is cubic, space group Ia-3d, with a =12.6093(2) Å, V = 2004.8(1)Å3, and Z = 8. The crystal structure was refined up to R1 = 0.0197 for 305 reflections with Fo > 4σ (Fo) and 19 parameters. Monteneveite is related to the other Ca-, Sb- and Fe-bearing, nominally Si-free members of the bitikleite group, but it differs in that it is the only known garnet species with mixed trivalent and divalent cations (2:1) at the tetrahedral Z site. Textural and mineralogical evidence suggests that monteneveite formed during peak metamorphism (at ca. 600 ºC) during partial breakdown of tetrahedrite-(Fe) by reactions with carbonate, under relatively oxidizingconditions. The mineral is named after the type locality, the Monteneve (Schneeberg) mine.

  • 35.
    Langhof, Jörgen
    et al.
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Holtstam, Dan
    Naturhistoriska riksmuseet, Enheten för geovetenskap. Swedish Museum of Natural History.
    Till minne av Paul B. Moore: Sverigevistelser och vetenskapligt arbete kring mineral av Långbantyp2019Inngår i: Långbansnytt, ISSN 1650-4968, Vol. 25, nr 1, s. 4-8Artikkel i tidsskrift (Annet (populærvitenskap, debatt, mm))
  • 36.
    Langhof, Jörgen
    et al.
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Karlsson, Andreas
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Holtstam, Dan
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Långban - a cornucopia for new mineral species?2021Konferansepaper (Annet vitenskapelig)
    Fulltekst (pdf)
    Långban - cornucopia
  • 37.
    Margheri, Simone
    et al.
    University of Florence.
    Bindi, Luca
    University of Florence.
    Bonazzi, Paola
    Università degli Studi di Firenze.
    Holtstam, Dan
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Structural and spectroscopic study of well-developed crystals of parahibbingite, β-Fe2(OH)3Cl, formed from terrestrial weathering of the Muonionalusta iron meteorite2022Inngår i: Mineralogical magazine, ISSN 0026-461X, E-ISSN 1471-8022, Vol. 86, nr 6, s. 891-896Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Parahibbingite [β-Fe2(OH)3Cl], a new mineral recently described from ultramafic rocks in the Bushveld Complex (South Africa), has been found to form millimetric well-developed crystals as a terrestrial weathering product of the Muonionalusta iron meteorite. The mineral, initially identified by means of Raman spectroscopy, was found in a small cavity within a crust of rust on a granitic rock fragment that was in direct contact with the alteration crust of a meteorite specimen, collected in the Kitkiöjärvi area (Sweden). Its crystal structure [a = 6.9362(4), c = 14.673(1) Å, V = 611.35(7) Å3 for Z = 6] was refined from single-crystal X-ray diffraction data (R1 = 0.0331) in the space group R-3m, thus confirming the structural model of synthetic β-Fe2(OH)3Cl. It consists of a network of octahedrally coordinated Fe2+ atoms alternatively arranged in triangular and Kagomé layers, stacked along the c axis. The H position was determined, showing O-H···Cl bonds which provide a further link between layers. Parahibbingite is found to be not only an important constituent of the corrosion system of archaeological iron artefacts but can also play an important role as an alteration product of iron meteorites.

    Fulltekst (pdf)
    fulltext
  • 38.
    Škoda, Radek
    et al.
    Masaryk University.
    Plasil, Jakub
    Institute of Physics ASCR.
    Čopjaková, Renata
    Masaryk University.
    Novak, Milan
    Masaryk University.
    Jonsson, Erik
    Uppsala Universitet.
    Vasinova Galiova, Michaela
    Masaryk University.
    Holtstam, Dan
    Naturhistoriska riksmuseet, Enheten för geovetenskap.
    Gadolinite-(Nd), a new member of the gadolinite supergroup from Fe-REE deposits of Bastnäs-type.2018Inngår i: Mineralogical magazine, ISSN 0026-461X, E-ISSN 1471-8022, Vol. 82(S1), s. S133-S145Artikkel i tidsskrift (Fagfellevurdert)
1 - 38 of 38
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